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1-Phenyl-1-trimethylsiloxyethylene, 95%, Thermo Scientific Chemicals

$50.44 - $170.44

Chemical Identifiers

CAS 13735-81-4
Molecular Formula C11H16OSi
Molecular Weight (g/mol) 192.333
MDL Number MFCD00008582
InChI Key AFFPCIMDERUIST-UHFFFAOYSA-N
Synonym 1-phenyl-1-trimethylsiloxyethylene, trimethyl 1-phenylvinyl oxy silane, 1-phenyl-1-trimethylsilyloxyethylene, 1-phenyl-1-trimethylsiloxy ethylene, 1-phenyl-1-trimethylsilyloxy ethylene, benzene, 1-trimethylsilyl oxy ethenyl, silane, trimethyl 1-phenylethenyl oxy, acmc-209ccf
PubChem CID 117406
IUPAC Name trimethyl(1-phenylethenoxy)silane
SMILES C[Si](C)(C)OC(=C)C1=CC=CC=C1
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Products 2
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL0530803
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Thermo Scientific Chemicals
L0530803
1 g
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AAL0530806
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Thermo Scientific Chemicals
L0530806
5 g
Each for $170.44
 
Description

Description

1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

Solubility
Reacts with water.

Notes
Store at 4°C. Moisture Sensitive. Store under inert gas. Incompatible materials are Oxidizing agents.
Specifications

Chemical Identifiers

13735-81-4
192.333
AFFPCIMDERUIST-UHFFFAOYSA-N
117406
C[Si](C)(C)OC(=C)C1=CC=CC=C1
C11H16OSi
MFCD00008582
1-phenyl-1-trimethylsiloxyethylene, trimethyl 1-phenylvinyl oxy silane, 1-phenyl-1-trimethylsilyloxyethylene, 1-phenyl-1-trimethylsiloxy ethylene, 1-phenyl-1-trimethylsilyloxy ethylene, benzene, 1-trimethylsilyl oxy ethenyl, silane, trimethyl 1-phenylethenyl oxy, acmc-209ccf
trimethyl(1-phenylethenoxy)silane

Specifications

53°C to 54°C (1mmHg)
1 g
MFCD00008582
78°C (172°F)
Reacts with water.
C[Si](C)(C)OC(=C)C1=CC=CC=C1
192.333
192.34
1.502
0.938
13735-81-4
C11H16OSi
1306914
1-phenyl-1-trimethylsiloxyethylene, trimethyl 1-phenylvinyl oxy silane, 1-phenyl-1-trimethylsilyloxyethylene, 1-phenyl-1-trimethylsiloxy ethylene, 1-phenyl-1-trimethylsilyloxy ethylene, benzene, 1-trimethylsilyl oxy ethenyl, silane, trimethyl 1-phenylethenyl oxy, acmc-209ccf
AFFPCIMDERUIST-UHFFFAOYSA-N
trimethyl(1-phenylethenoxy)silane
117406
97%
Moisture sensitive
1-Phenyl-1-trimethylsiloxyethylene
Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.

P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

H227-H315-H319-H335

EINECSNumber : 237-308-1

TSCA : Yes

Recommended Storage : Keep cold; Store under Nitrogen

SDS
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RUO – Research Use Only