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Alfa Aesar™ 1,3-Bis(diphenylphosphino)propane, 97%

$78.41 - $263.61

Chemical Identifiers

Chemical Name or Material 1,3-Bis(diphenylphosphino)propane
CAS 6737-42-4
Molecular Formula C27H26P2
Linear Formula (C6H5)2P(CH2)3P(C6H5)2
Formula Weight 412.46g/mol
MDL Number MFCD00003050
Beilstein 2821785
Synonym Dppp
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1293114

 
alfa aesar™
A12931-14
25g Each for $263.61

AAA1293106

 
alfa aesar™
A12931-06
5g Each for $78.41
Description & Specifications

Specifications

Melting Point 58° to 63°C
Quantity 25g
Chemical Name or Material 1,3-Bis(diphenylphosphino)propane
CAS 6737-42-4
Assay 97%
Molecular Formula C27H26P2
Linear Formula (C6H5)2P(CH2)3P(C6H5)2
Formula Weight 412.46g/mol
MDL Number MFCD00003050
Beilstein 2821785
Synonym Dppp
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
TSCA TSCA

Applications
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Solubility
Insoluble in water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.