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Alfa Aesar™ 1,3-Bis(diphenylphosphino)propane, 97%

$84.82 - $284.78

Chemical Identifiers

Chemical Name or Material 1,3-Bis(diphenylphosphino)propane
CAS 6737-42-4
Molecular Formula C27H26P2
Linear Formula (C6H5)2P(CH2)3P(C6H5)2
Formula Weight 412.46
MDL Number MFCD00003050
Beilstein 2821785
Synonym Dppp
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1293114

  SDS
alfa aesar™
A1293114
25g Each for $284.78

AAA1293106

  SDS
alfa aesar™
A1293106
5g Each for $84.82
Description & Specifications

Specifications

Formula Weight 412.46
Synonym Dppp
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical Name or Material 1,3-Bis(diphenylphosphino)propane
Assay 97%
Health Hazard 1 Warning
TSCA TSCA
MDL Number MFCD00003050
CAS 6737-42-4
Beilstein 2821785
Molecular Formula C27H26P2
Linear Formula (C6H5)2P(CH2)3P(C6H5)2
Quantity 25g
Melting Point 58° to 63°C

Applications
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Solubility
Insoluble in water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.