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Alfa Aesar™ 1,3-Bis(diphenylphosphino)propane, 97%

$86.66 - $290.92

Chemical Identifiers

CAS 6737-42-4
Molecular Formula C27H26P2
Linear Formula (C6H5)2P(CH2)3P(C6H5)2
Formula Weight 412.46
MDL Number MFCD00003050
Beilstein 2821785
Synonym Dppp
Chemical Name or Material 1,3-Bis(diphenylphosphino)propane
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAA1293114 SDS Alfa Aesar™
A1293114
25g Each for $290.92
AAA1293106 SDS Alfa Aesar™
A1293106
5g Each for $86.66
AAA1293122 SDS Alfa Aesar™
A1293122
100g N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Specifications

Description

Applications
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Solubility
Insoluble in water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.
Description & Specifications

Chemical Identifiers

6737-42-4
(C6H5)2P(CH2)3P(C6H5)2
MFCD00003050
Dppp
C27H26P2
412.46
2821785
1,3-Bis(diphenylphosphino)propane

Specifications

6737-42-4
(C6H5)2P(CH2)3P(C6H5)2
MFCD00003050
Dppp
25g
97%
C27H26P2
412.46
2821785
58° to 63°C
1,3-Bis(diphenylphosphino)propane

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Warning

TSCA : TSCA