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Alfa Aesar™ 1,1'-Bis(diphenylphosphino)ferrocene, 97%

$547.93 - $547.93

Chemical Identifiers

Chemical Name or Material 1,1'-Bis(diphenylphosphino)ferrocene
CAS 12150-46-8
Molecular Formula C34H28FeP2
Formula Weight 554.40g/mol
MDL Number MFCD00001422
Synonym 1,1'-Ferrocenebis(diphenylphosphine)
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAB2116614

 
alfa aesar
B21166-14
25g Each for $547.93
Description & Specifications

Specifications

Melting Point ≈182°C (dec.)
Quantity 25g
Chemical Name or Material 1,1'-Bis(diphenylphosphino)ferrocene
CAS 12150-46-8
Assay 97%
Assay Percent Range 0.97
Molecular Formula C34H28FeP2
Formula Weight 554.40g/mol
MDL Number MFCD00001422
Synonym 1,1'-Ferrocenebis(diphenylphosphine)
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Storage Note 1 Air Sensitive
Recommended Storage 2° to 8°C

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.